Ultimate analysis of solid and liquid fuels

Thermodynamics

| June 18, 2022, 9:55 p.m.

Coal and petroleum are the widely used fuels in the world. Although researchers are experimenting with new sustainable energy sources, fossil fuels are still a mainstay of the energy supply around the world and will remain for several decades. For effective utilization of energy from these fuels, it is important to know the composition of the fuel. Knowledge of what fuel is really made up of will help in improving the performance of systems utilizing them.

There are mainly two types of methods being used in analyzing the composition of the fuel, proximate analysis and ultimate analysis.

1. Proximate analysis

This method generally determines macro parameters of the fuel, such as moisture content, volatile matter, fixed carbon, CCR, acidity, and ash content. This method is more useful for commercial purposes and framing regulatory requirements.

2. Ultimate analysis

The ultimate analysis of fuel determines the elemental composition of the fuel, that is the percentage of carbon, hydrogen, sulfur, oxygen, nitrogen, and ash. This can be more useful in the combustion analysis of fuel. It is always better to use test results of actual fuel, however for initial calculations, the ultimate analysis given in the tables below can be used. Values that are unknown, are represented by "-".

Ultimate analysis of common solid fuels (by mass)

Fuel

Carbon

Hydrogen

Oxygen

Nitrogen

Sulfur

Incombustible

Higher calorific value (kJ/kg K)

Bituminous

81

5

8

1.5

1

3.5

33500

Peat (dry)

58

6.3

30.8

0.9

-

4

19700

Lignite

66

5

20

1

1

3.5

21650

Anthracite

91

3

-

-

-

-

34600

Work (dry)

48.5

6

43.5

0.5

-

1.5

17300

 

Ultimate analysis of common liquid fuels (by mass)

Fuel

Specific gravity

Carbon

Hydrogen

Sulfur

Lower calorific value (kJ/kg K)

Higher calorific value (kJ/kg K)

Gasoline

0.74

85.4

14.6

-

43700

46820

Diesel oil

0.87

86.3

12.8

0.9

43250

46000

Paraffin

0.79

86.3

13.6

0.1

43250

46250

Heavy oil

0.95

86.1

11.8

2.1

41300

44000